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Francisco de Asís Capet de Borbón, Duke of Cádiz, was born 13 May 1822 in Aranjuez, Spain to Francisco de Paula de España (1794-1865) and Luisa Carlotta di Borbone delle Due Sicilie (1804-1844) and died 17 April 1902 Épinay-sur-Seine, France of unspecified causes. He married Isabella II de España (1830-1904) 10 October 1874 .
Children
| Name | Birth | Death | Joined with |
| Fernando de España (1850-1850) | |||
| Maria Isabel de España (1851-1931) | |||
| Maria Cristina de España (1854-1854) | |||
| Alfonso XII de España (1857-1885) | 28 November 1857 Madrid, Spain | 25 November 1885 El Pardo, Spain | Mercedes of Orléans (1860-1878) Maria Christina von Österreich (1858-1929) |
| Maria de la Concepcion de España (1859-1861) | |||
| Maria del Pilar de España (1861-1879) | |||
| María de la Paz de España (1862-1946) | |||
| Francisco de Asis de España (1863-1863) | |||
| Eulalia de Asis de la Piedad de España (1864-1958) | 12 February 1864 Madrid, Spain | 8 March 1958 Irun, Spain | Antonio of Orléans (1866-1930) |